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Impact of Green Cosolvents on the Catalytic Dehydrogenation of Formic Acid: The Case of Iridium Catalysts Bearing NHC-phosphane Ligands

[Image: see text] The catalysts [Ir(COD)(κ(3)-P,C,P′-PC(NHC)P)]BF(4) and [Ir(COD)(κ(2)-P,C-PC(NHC)O)]BF(4) proved to be active in the solventless dehydrogenation of formic acid. The impact of various cosolvents on the activity was evaluated, showing an outstanding improvement of the catalytic perfor...

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Detalles Bibliográficos
Autores principales: Luque-Gómez, Ana, García-Abellán, Susana, Munarriz, Julen, Polo, Victor, Passarelli, Vincenzo, Iglesias, Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8527458/
https://www.ncbi.nlm.nih.gov/pubmed/34558914
http://dx.doi.org/10.1021/acs.inorgchem.1c02132