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Impact of Green Cosolvents on the Catalytic Dehydrogenation of Formic Acid: The Case of Iridium Catalysts Bearing NHC-phosphane Ligands
[Image: see text] The catalysts [Ir(COD)(κ(3)-P,C,P′-PC(NHC)P)]BF(4) and [Ir(COD)(κ(2)-P,C-PC(NHC)O)]BF(4) proved to be active in the solventless dehydrogenation of formic acid. The impact of various cosolvents on the activity was evaluated, showing an outstanding improvement of the catalytic perfor...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8527458/ https://www.ncbi.nlm.nih.gov/pubmed/34558914 http://dx.doi.org/10.1021/acs.inorgchem.1c02132 |