Cargando…
Actinide arene-metalates: ion pairing effects on the electronic structure of unsupported uranium–arenide sandwich complexes
Addition of [UI(2)(THF)(3)(μ-OMe)](2)·THF (2·THF) to THF solutions containing 6 equiv. of K[C(14)H(10)] generates the heteroleptic dimeric complexes [K(18-crown-6)(THF)(2)](2)[U(η(6)-C(14)H(10))(η(4)-C(14)H(10))(μ-OMe)](2)·4THF (118C6·4THF) and {[K(THF)(3)][U(η(6)-C(14)H(10))(η(4)-C(14)H(10))(μ-OMe)...
Autores principales: | , , , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8528047/ https://www.ncbi.nlm.nih.gov/pubmed/34777754 http://dx.doi.org/10.1039/d1sc03275e |