Actinide arene-metalates: ion pairing effects on the electronic structure of unsupported uranium–arenide sandwich complexes

Addition of [UI(2)(THF)(3)(μ-OMe)](2)·THF (2·THF) to THF solutions containing 6 equiv. of K[C(14)H(10)] generates the heteroleptic dimeric complexes [K(18-crown-6)(THF)(2)](2)[U(η(6)-C(14)H(10))(η(4)-C(14)H(10))(μ-OMe)](2)·4THF (118C6·4THF) and {[K(THF)(3)][U(η(6)-C(14)H(10))(η(4)-C(14)H(10))(μ-OMe)...

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Detalles Bibliográficos
Autores principales: Murillo, Jesse, Bhowmick, Rina, Harriman, Katie L. M., Gomez-Torres, Alejandra, Wright, Joshua, Meulenberg, Robert W., Miró, Pere, Metta-Magaña, Alejandro, Murugesu, Muralee, Vlaisavljevich, Bess, Fortier, Skye
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8528047/
https://www.ncbi.nlm.nih.gov/pubmed/34777754
http://dx.doi.org/10.1039/d1sc03275e

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