Coinage metal aluminyl complexes: probing regiochemistry and mechanism in the insertion and reduction of carbon dioxide

The synthesis of coinage metal aluminyl complexes, featuring M–Al covalent bonds, is reported via a salt metathesis approach employing an anionic Al(i) (‘aluminyl’) nucleophile and group 11 electrophiles. This approach allows access to both bimetallic (1 : 1) systems of the type ((t)Bu(3)P)MAl(NON)...

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Detalles Bibliográficos
Autores principales: McManus, Caitilín, Hicks, Jamie, Cui, Xianlu, Zhao, Lili, Frenking, Gernot, Goicoechea, Jose M., Aldridge, Simon
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8528051/
https://www.ncbi.nlm.nih.gov/pubmed/34777765
http://dx.doi.org/10.1039/d1sc04676d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8528051/
https://www.ncbi.nlm.nih.gov/pubmed/34777765
http://dx.doi.org/10.1039/d1sc04676d

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