The origin of the particle-size-dependent selectivity in 1-butene isomerization and hydrogenation on Pd/Al(2)O(3) catalysts

The selectivity of 1-butene hydrogenation/isomerization on Pd catalysts is known to be particle size dependent. Here we show that combining well-defined model catalysts, atmospheric pressure reaction kinetics, DFT calculations and microkinetic modeling enables to rationalize the particle size effect...

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Detalles Bibliográficos
Autores principales: Genest, Alexander, Silvestre-Albero, Joaquín, Li, Wen-Qing, Rösch, Notker, Rupprechter, Günther
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8528898/
https://www.ncbi.nlm.nih.gov/pubmed/34671045
http://dx.doi.org/10.1038/s41467-021-26411-8

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8528898/
https://www.ncbi.nlm.nih.gov/pubmed/34671045
http://dx.doi.org/10.1038/s41467-021-26411-8

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