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The origin of the particle-size-dependent selectivity in 1-butene isomerization and hydrogenation on Pd/Al(2)O(3) catalysts

The selectivity of 1-butene hydrogenation/isomerization on Pd catalysts is known to be particle size dependent. Here we show that combining well-defined model catalysts, atmospheric pressure reaction kinetics, DFT calculations and microkinetic modeling enables to rationalize the particle size effect...

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Detalles Bibliográficos
Autores principales:	Genest, Alexander, Silvestre-Albero, Joaquín, Li, Wen-Qing, Rösch, Notker, Rupprechter, Günther
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2021
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8528898/ https://www.ncbi.nlm.nih.gov/pubmed/34671045 http://dx.doi.org/10.1038/s41467-021-26411-8

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