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Quadruple C–H Bond Activations of Methane by Dinuclear Rhodium Carbide Cation [Rh(2)C(3)](+)
[Image: see text] The structure of the [Rh(2)C(3)](+) ion and its reaction with CH(4) in the gas phase have been studied by infrared photodissociation spectroscopy and mass spectrometry in conjunction with quantum chemical calculations. The [Rh(2)C(3)](+) ion is characterized to have an unsymmetrica...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8549038/ https://www.ncbi.nlm.nih.gov/pubmed/34723266 http://dx.doi.org/10.1021/jacsau.1c00265 |