Chromophore-radical excited state antiferromagnetic exchange controls the sign of photoinduced ground state spin polarization

A change in the sign of the ground-state electron spin polarization (ESP) is reported in complexes where an organic radical (nitronylnitroxide, NN) is covalently attached to a donor–acceptor chromophore via two different meta-phenylene bridges in (bpy)Pt(CAT-m-Ph-NN) (mPh-Pt) and (bpy)Pt(CAT-6-Me-m-...

Descripción completa

Detalles Bibliográficos
Autores principales: Kirk, Martin L., Shultz, David A., Hewitt, Patrick, Stasiw, Daniel E., Chen, Ju, van der Est, Art
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8549796/
https://www.ncbi.nlm.nih.gov/pubmed/34760154
http://dx.doi.org/10.1039/d1sc02965g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8549796/
https://www.ncbi.nlm.nih.gov/pubmed/34760154
http://dx.doi.org/10.1039/d1sc02965g

Ejemplares similares