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Chromophore-radical excited state antiferromagnetic exchange controls the sign of photoinduced ground state spin polarization

A change in the sign of the ground-state electron spin polarization (ESP) is reported in complexes where an organic radical (nitronylnitroxide, NN) is covalently attached to a donor–acceptor chromophore via two different meta-phenylene bridges in (bpy)Pt(CAT-m-Ph-NN) (mPh-Pt) and (bpy)Pt(CAT-6-Me-m-...

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Detalles Bibliográficos
Autores principales:	Kirk, Martin L., Shultz, David A., Hewitt, Patrick, Stasiw, Daniel E., Chen, Ju, van der Est, Art
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2021
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8549796/ https://www.ncbi.nlm.nih.gov/pubmed/34760154 http://dx.doi.org/10.1039/d1sc02965g

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