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Enantioselective palladium-catalyzed C(sp(2))–C(sp(2)) σ bond activation of cyclopropenones by merging desymmetrization and (3 + 2) spiroannulation with cyclic 1,3-diketones
Catalytic asymmetric variants for functional group transformations based on carbon–carbon bond activation still remain elusive. Herein we present an unprecedented palladium-catalyzed (3 + 2) spiro-annulation merging C(sp(2))–C(sp(2)) σ bond activation and click desymmetrization to form synthetically...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8549799/ https://www.ncbi.nlm.nih.gov/pubmed/34760158 http://dx.doi.org/10.1039/d1sc04558j |