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Silicon as a powerful control element in HDDA chemistry: redirection of innate cyclization preferences, functionalizable tethers, and formal bimolecular HDDA reactions

The 1,3-diyne and diynophile in hexadehydro-Diels–Alder (HDDA) reaction substrates are typically tethered by linker units that consist of C, O, N, and/or S atoms. We describe here a new class of polyynes based on silicon-containing tethers that can be disposed of and/or functionalized subsequent to...

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Detalles Bibliográficos
Autores principales: Lynn, Mandy, Pierson Smela, Merrick, Hoye, Thomas R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8549800/
https://www.ncbi.nlm.nih.gov/pubmed/34760176
http://dx.doi.org/10.1039/d1sc04082k