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Reactivity Properties of Mixed- and High-Valent Bis(μ-Hydroxide)-Dinickel Complexes

[Image: see text] Despite their potential role in enzymatic systems, there is a dearth of hydroxide-bridged high-valent oxidants. We recently reported the synthesis and characterization of Ni(II)Ni(III)(μ-OH)(2) (2) and Ni(2)(III)(μ-OH)(2) (3) species supported by a dicarboxamidate ligand (N,N′-bis(...

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Detalles Bibliográficos
Autores principales: Spedalotto, Giuseppe, Lovisari, Marta, McDonald, Aidan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8554787/
https://www.ncbi.nlm.nih.gov/pubmed/34723014
http://dx.doi.org/10.1021/acsomega.1c04225