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Ligand-dependent stereoselective Suzuki–Miyaura cross-coupling reactions of β-enamido triflates

The stereoselective Suzuki–Miyaura cross-coupling of (Z)-β-enamido triflates is demonstrated. Depending on the nature of the ligand in the palladium catalyst, either retention or inversion of the configuration during the synthesis of β,β-diaryl-substituted enamides is observed. Thus, the method prov...

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Detalles Bibliográficos
Autores principales: Chvojka, Tomáš, Markos, Athanasios, Voltrová, Svatava, Pohl, Radek, Beier, Petr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8561141/
https://www.ncbi.nlm.nih.gov/pubmed/34795803
http://dx.doi.org/10.3762/bjoc.17.179