Atomically Precise Ni–Pd Alloy Carbonyl Nanoclusters: Synthesis, Total Structure, Electrochemistry, Spectroelectrochemistry, and Electrochemical Impedance Spectroscopy

[Image: see text] The molecular nanocluster [Ni(36–x)Pd(5+x)(CO)(46)](6–) (x = 0.41) (1(6–)) was obtained from the reaction of [NMe(3)(CH(2)Ph)](2)[Ni(6)(CO)(12)] with 0.8 molar equivalent of [Pd(CH(3)CN)(4)][BF(4)](2) in tetrahydrofuran (thf). In contrast, [Ni(37–x)Pd(7+x)(CO)(48)](6–) (x = 0.69) (...

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Detalles Bibliográficos
Autores principales: Cesari, Cristiana, Funaioli, Tiziana, Berti, Beatrice, Femoni, Cristina, Iapalucci, Maria Carmela, Vivaldi, Federico Maria, Zacchini, Stefano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8564757/
https://www.ncbi.nlm.nih.gov/pubmed/34672566
http://dx.doi.org/10.1021/acs.inorgchem.1c02582

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8564757/
https://www.ncbi.nlm.nih.gov/pubmed/34672566
http://dx.doi.org/10.1021/acs.inorgchem.1c02582

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