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Chromium carbides and cyclopropenylidenes

Carbon tetrabromide can be reduced with CrBr(2) in THF to form a dinuclear carbido complex, [CrBr(2)(thf)(2))][CrBr(2)(thf)(3)](μ-C), along with formation of [CrBr(3)(thf)(3)]. An X-ray diffraction (XRD) study of the pyridine adduct displayed a dinuclear structure bridged by a carbido ligand between...

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Detalles Bibliográficos
Autores principales: Kurogi, Takashi, Irifune, Keiichi, Takai, Kazuhiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8565369/
https://www.ncbi.nlm.nih.gov/pubmed/34760214
http://dx.doi.org/10.1039/d1sc04910k