Cooperative C–H activation of pyridine by PBP complexes of Rh and Ir can lead to bridging 2-pyridyls with different connectivity to the B–M unit

Pyridine and quinoline undergo selective C–H activation in the 2-position with Rh and Ir complexes of a boryl/bis(phosphine) PBP pincer ligand, resulting in a 2-pyridyl bridging the transition metal and the boron center. Examination of this reactivity with Rh and Ir complexes carrying different non-...

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Detalles Bibliográficos
Autores principales: Cao, Yihan, Shih, Wei-Chun, Bhuvanesh, Nattamai, Zhou, Jia, Ozerov, Oleg V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8565379/
https://www.ncbi.nlm.nih.gov/pubmed/34760201
http://dx.doi.org/10.1039/d1sc01850g

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8565379/
https://www.ncbi.nlm.nih.gov/pubmed/34760201
http://dx.doi.org/10.1039/d1sc01850g

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