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Functional and protective hole hopping in metalloenzymes

Electrons can tunnel through proteins in microseconds with a modest release of free energy over distances in the 15 to 20 Å range. To span greater distances, or to move faster, multiple charge transfers (hops) are required. When one of the reactants is a strong oxidant, it is convenient to consider...

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Detalles Bibliográficos
Autores principales: Gray, Harry B., Winkler, Jay R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8565380/
https://www.ncbi.nlm.nih.gov/pubmed/34760183
http://dx.doi.org/10.1039/d1sc04286f