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Functional and protective hole hopping in metalloenzymes
Electrons can tunnel through proteins in microseconds with a modest release of free energy over distances in the 15 to 20 Å range. To span greater distances, or to move faster, multiple charge transfers (hops) are required. When one of the reactants is a strong oxidant, it is convenient to consider...
Autores principales: | Gray, Harry B., Winkler, Jay R. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8565380/ https://www.ncbi.nlm.nih.gov/pubmed/34760183 http://dx.doi.org/10.1039/d1sc04286f |
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