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The Nonphysiological Reductant Sodium Dithionite and [FeFe] Hydrogenase: Influence on the Enzyme Mechanism

[Image: see text] [FeFe] hydrogenases are highly active enzymes for interconverting protons and electrons with hydrogen (H(2)). Their active site H-cluster is formed of a canonical [4Fe-4S] cluster ([4Fe-4S](H)) covalently attached to a unique [2Fe] subcluster ([2Fe](H)), where both sites are redox...

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Detalles Bibliográficos
Autores principales: Martini, Maria Alessandra, Rüdiger, Olaf, Breuer, Nina, Nöring, Birgit, DeBeer, Serena, Rodríguez-Maciá, Patricia, Birrell, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8569811/
https://www.ncbi.nlm.nih.gov/pubmed/34668697
http://dx.doi.org/10.1021/jacs.1c07322