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The Nonphysiological Reductant Sodium Dithionite and [FeFe] Hydrogenase: Influence on the Enzyme Mechanism
[Image: see text] [FeFe] hydrogenases are highly active enzymes for interconverting protons and electrons with hydrogen (H(2)). Their active site H-cluster is formed of a canonical [4Fe-4S] cluster ([4Fe-4S](H)) covalently attached to a unique [2Fe] subcluster ([2Fe](H)), where both sites are redox...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8569811/ https://www.ncbi.nlm.nih.gov/pubmed/34668697 http://dx.doi.org/10.1021/jacs.1c07322 |