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Kinetics of NH(3) Desorption and Diffusion on Pt: Implications for the Ostwald Process

[Image: see text] We report accurate time-resolved measurements of NH(3) desorption from Pt(111) and Pt(332) and use these results to determine elementary rate constants for desorption from steps, from (111) terrace sites and for diffusion on (111) terraces. Modeling the extracted rate constants wit...

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Detalles Bibliográficos
Autores principales: Borodin, Dmitriy, Rahinov, Igor, Galparsoro, Oihana, Fingerhut, Jan, Schwarzer, Michael, Golibrzuch, Kai, Skoulatakis, Georgios, Auerbach, Daniel J., Kandratsenka, Alexander, Schwarzer, Dirk, Kitsopoulos, Theofanis N., Wodtke, Alec M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8569812/
https://www.ncbi.nlm.nih.gov/pubmed/34672570
http://dx.doi.org/10.1021/jacs.1c09269