Silylboronate-Mediated Defluorosilylation of Aryl Fluorides with or without Ni-Catalyst

The defluorosilylation of aryl fluorides to access aryl silanes was achieved under transition-metal-free conditions via an inert C–F bond activation. The defluorosilylation, mediated by silylboronates and KOtBu, proceeded smoothly at room temperature to afford various aryl silanes in good yields. Al...

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Detalles Bibliográficos
Autores principales: Zhou, Jun, Zhao, Zhengyu, Shibata, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2021
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8573161/
https://www.ncbi.nlm.nih.gov/pubmed/34760872
http://dx.doi.org/10.3389/fchem.2021.771473

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8573161/
https://www.ncbi.nlm.nih.gov/pubmed/34760872
http://dx.doi.org/10.3389/fchem.2021.771473

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