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Accelerated Vibrational Energy Relaxation of Water in Alkaline Environments

[Image: see text] We observe that hydrated hydroxide ions introduce an additional relaxation channel for the vibrational relaxation of the OD vibrations of HDO molecules in aqueous NaOH solutions. This additional relaxation path involves resonant (Förster) vibrational energy transfer from the excite...

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Detalles Bibliográficos
Autores principales: Cota, Roberto, Woutersen, Sander, Bakker, Huib J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8573739/
https://www.ncbi.nlm.nih.gov/pubmed/34672577
http://dx.doi.org/10.1021/acs.jpcb.1c02730