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Flexibility Enhances Reactivity: Redox Isomerism and Jahn–Teller Effects in a Bioinspired Mn(4)O(4) Cubane Water Oxidation Catalyst
[Image: see text] Understanding how water oxidation to molecular oxygen proceeds in molecular metal-oxo catalysts is a challenging endeavor due to their structural complexity. In this report, we unravel the water oxidation mechanism of the highly active water oxidation catalyst [Mn(4)V(4)O(17)(OAc)(...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8576808/ https://www.ncbi.nlm.nih.gov/pubmed/34777908 http://dx.doi.org/10.1021/acscatal.1c03566 |