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Flexibility Enhances Reactivity: Redox Isomerism and Jahn–Teller Effects in a Bioinspired Mn(4)O(4) Cubane Water Oxidation Catalyst

[Image: see text] Understanding how water oxidation to molecular oxygen proceeds in molecular metal-oxo catalysts is a challenging endeavor due to their structural complexity. In this report, we unravel the water oxidation mechanism of the highly active water oxidation catalyst [Mn(4)V(4)O(17)(OAc)(...

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Detalles Bibliográficos
Autores principales:	Schwiedrzik, Ludwig, Brieskorn, Vera, González, Leticia
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2021
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8576808/ https://www.ncbi.nlm.nih.gov/pubmed/34777908 http://dx.doi.org/10.1021/acscatal.1c03566

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