1,5-Hydrogen Atom Transfer/Surzur–Tanner Rearrangement: A Radical Cascade Approach for the Synthesis of 1,6-Dioxaspiro[4.5]decane and 6,8-Dioxabicyclo[3.2.1]octane Scaffolds in Carbohydrate Systems

[Image: see text] The 1,5-HAT–1,2-(ester)alkyl radical migration (Surzur–Tanner rearrangement) radical/polar sequence triggered by alkoxyl radicals has been studied on a series of C-glycosyl substrates with 3-C-(α,β-d,l-glycopyranosyl)1-propanol and C-(α-d,l-glycopyranosyl)methanol structures prepar...

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Detalles Bibliográficos
Autores principales: León, Elisa I., Martín, Ángeles, Montes, Adrián S., Pérez-Martín, Inés, del Sol Rodríguez, María, Suárez, Ernesto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2021
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8576821/
https://www.ncbi.nlm.nih.gov/pubmed/34554734
http://dx.doi.org/10.1021/acs.joc.1c01376

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8576821/
https://www.ncbi.nlm.nih.gov/pubmed/34554734
http://dx.doi.org/10.1021/acs.joc.1c01376

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