Cargando…
The porphyrin center as a regulator for metal–ligand covalency and π hybridization in the entire molecule
The central moiety of porphyrins is shown to control the charge state of the inner complex and links it by covalent interaction to the peripheral substituents. This link, which enables the versatile functions of porphyrins, is not picked up in the established, reduced four orbital picture [Gouterman...
| Autores principales: | , , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8579471/ https://www.ncbi.nlm.nih.gov/pubmed/34714305 http://dx.doi.org/10.1039/d1cp03944j |