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Isolation of a planar 1,2-dilithio-disilene and its conversion to a Si–B hybrid 2π-electron system and a planar tetraboryldisilene
Lithium reagents have long played important roles in synthetic chemistry. However, unsaturated organosilicon lithium reagents are few in number. Herein, we describe the first isolation of a 1,2-dilithiodisilene: [(boryl)SiLi](2) (2) was prepared in 73% yield by the reduction of (boryl)tribromosilane...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8580061/ https://www.ncbi.nlm.nih.gov/pubmed/34881016 http://dx.doi.org/10.1039/d1sc05125c |