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In Search of the Perfect Triple BB Bond: Mechanical Tuning of the Host Molecular Trap for the Triple Bond B≡B Fragment
The coordination of the B(2) fragment by two σ-donor ligands L: could lead to a diboryne compound with a formal triple bond L:→B≡B←:L. σ-Type coordination L:→B leads to an excess of electrons around the B(2) central fragment, whereas π-back-donation from the B≡B moiety to ligand L has a compensation...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8587956/ https://www.ncbi.nlm.nih.gov/pubmed/34770837 http://dx.doi.org/10.3390/molecules26216428 |