Synthesis of Boronated Amidines by Addition of Amines to Nitrilium Derivative of Cobalt Bis(Dicarbollide) †

A series of novel cobalt bis(dicarbollide) based amidines were synthesized by the nucleophilic addition of primary and secondary amines to highly activated B-N(+)≡C–R triple bond of the propionitrilium derivative [8-EtC≡N-3,3′-Co(1,2-C(2)B(9)H(10))(1′,2′-C(2)B(9)H(11))]. The reactions with primary a...

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Detalles Bibliográficos
Autores principales: Bogdanova, Ekaterina V., Stogniy, Marina Yu., Suponitsky, Kyrill Yu., Sivaev, Igor B., Bregadze, Vladimir I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8588172/
https://www.ncbi.nlm.nih.gov/pubmed/34770953
http://dx.doi.org/10.3390/molecules26216544

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8588172/
https://www.ncbi.nlm.nih.gov/pubmed/34770953
http://dx.doi.org/10.3390/molecules26216544

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