Regio- and enantioselective umpolung gem-difluoroallylation of hydrazones via palladium catalysis enabled by N-heterocyclic carbene ligand

The enantioselective construction of C–CF(2)R (R: alkyl or fluoroalkyl) bonds has attracted the attention of synthetic chemists because of the importance of chiral fluorinated compounds in life and materials sciences. Catalytic asymmetric fluoroalkylation has mainly been realized under organocatalys...

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Detalles Bibliográficos
Autores principales: Huang, Shuai, Tong, Fei-Fei, Bai, Da-Chang, Zhang, Gao-Peng, Jiang, Yang-Jie, Zhang, Bo, Leng, Xuebing, Guo, Ying-Long, Wan, Xiao-Long, Zhang, Xingang, Ding, Chang-Hua, Hou, Xue-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8589859/
https://www.ncbi.nlm.nih.gov/pubmed/34772944
http://dx.doi.org/10.1038/s41467-021-26667-0

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8589859/
https://www.ncbi.nlm.nih.gov/pubmed/34772944
http://dx.doi.org/10.1038/s41467-021-26667-0

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