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Concise Total Synthesis of Agarozizanol B via a Strained Photocascade Intermediate

The prezizane‐type sesquiterpene agarozizanol B was synthesized employing a photochemical cascade reaction as the key step. Starting from a readily available 1‐indanone with a tethered olefin, a strained tetracyclic skeleton was assembled which contained all carbon atoms of the sesquiterpene with th...

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Detalles Bibliográficos
Autores principales: Rauscher, Niklas, Næsborg, Line, Jandl, Christian, Bach, Thorsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596452/
https://www.ncbi.nlm.nih.gov/pubmed/34519408
http://dx.doi.org/10.1002/anie.202110009