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Alkali Metal Complexes of a Bis(diphenylphosphino)methane Functionalized Amidinate Ligand: Synthesis and Luminescence

A novel bis(diphenylphosphino)methane (DPPM) functionalized amidine ligand (DPPM−C(N‐Dipp)(2)H) (Dipp=2,6‐diisopropylphenyl) was synthesized. Subsequent deprotonation with suitable alkali metal bases resulted in the corresponding complexes [M{DPPM−C(N‐Dipp)(2)}(L(n))] (M=Li, Na, K, Rb, Cs; L=thf, Et...

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Detalles Bibliográficos
Autores principales: Zovko, Christina, Schoo, Christoph, Feuerstein, Thomas J., Münzfeld, Luca, Knöfel, Nicolai D., Lebedkin, Sergei, Kappes, Manfred M., Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596514/
https://www.ncbi.nlm.nih.gov/pubmed/34427374
http://dx.doi.org/10.1002/chem.202102243