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Direct Evidence on the Mechanism of Methane Conversion under Non‐oxidative Conditions over Iron‐modified Silica: The Role of Propargyl Radicals Unveiled

Radical‐mediated gas‐phase reactions play an important role in the conversion of methane under non‐oxidative conditions into olefins and aromatics over iron‐modified silica catalysts. Herein, we use operando photoelectron photoion coincidence spectroscopy to disentangle the elusive C(2+) radical int...

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Detalles Bibliográficos
Autores principales:	Puente‐Urbina, Allen, Pan, Zeyou, Paunović, Vladimir, Šot, Petr, Hemberger, Patrick, van Bokhoven, Jeroen Anton
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596584/ https://www.ncbi.nlm.nih.gov/pubmed/34459534 http://dx.doi.org/10.1002/anie.202107553

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