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Rational Design of a Confacial Pentaoctahedron: Anisotropic Exchange in a Linear Zn(II)Fe(III)Fe(III)Fe(III)Zn(II) Complex

The first confacial pentaoctahedron comprised of transition metal ions namely Zn(II)Fe(III) (A)Fe(III) (B)Fe(III) (A)Zn(II) has been synthesized by using a dinucleating nonadentate ligand. The face‐sharing bridging mode enforces short Zn(II)⋅⋅⋅Fe(III) (A) and Fe(III) (A)⋅⋅⋅Fe(III) (B) distances of 2...

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Detalles Bibliográficos
Autores principales: Walleck, Stephan, Atanasov, Mihail, Schnack, Jürgen, Bill, Eckhard, Stammler, Anja, Bögge, Hartmut, Glaser, Thorsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596665/
https://www.ncbi.nlm.nih.gov/pubmed/34427372
http://dx.doi.org/10.1002/chem.202102572