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Excited State Charge Separation in an Azobenzene‐Bridged Perylenediimide Dimer – Effect of Photochemical Trans‐Cis Isomerization

Photoinduced charge transfer and separation events in a newly synthesized azobenzene‐bridged perylenediimide‐dimer (PDI‐dimer) are demonstrated. Trans‐to‐cis conversion (∼50 % efficiency) from the initial trans PDI‐dimer by 355 nm pulsed laser light, and its reversal, cis‐to‐trans, process by 435 nm...

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Detalles Bibliográficos
Autores principales: Zink‐Lorre, Nathalie, Seetharaman, Sairaman, Gutiérrez‐Moreno, David, Fernández‐Lázaro, Fernando, Karr, Paul A., D'Souza, Francis
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596671/
https://www.ncbi.nlm.nih.gov/pubmed/34405918
http://dx.doi.org/10.1002/chem.202102903