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Direct Photoexcitation of Ethynylbenziodoxolones: An Alternative to Photocatalysis for Alkynylation Reactions

Ethynylbenziodoxolones (EBXs) are commonly used as radical traps in photocatalytic alkynylations. Herein, we report that aryl‐substituted EBX reagents can be directly activated by visible light irradiation. They act as both oxidants and radical traps, alleviating the need for a photocatalyst in seve...

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Detalles Bibliográficos
Autores principales: Amos, Stephanie G. E., Cavalli, Diana, Le Vaillant, Franck, Waser, Jerome
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596672/
https://www.ncbi.nlm.nih.gov/pubmed/34403571
http://dx.doi.org/10.1002/anie.202110257