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Scandium Reduced Arene Complex: Protonation and Reaction with Azobenzene

The reactivity of the reduced anthracene complex of scandium [Li(thf)(3)][Sc{N(tBu)Xy}(2)(anth)] (2‐anth‐Li) (Xy=3,5‐Me(2)C(6)H(3); anth=C(14)H(10) (2−), thf=tetrahydrofuran) toward Brønsted acid [NEt(3)H][BPh(4)] and azobenzene is reported. While a stepwise protonation of 2‐anth‐Li with two equival...

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Detalles Bibliográficos
Autores principales: Ghana, Priyabrata, Spaniol, Thomas P., Okuda, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596697/
https://www.ncbi.nlm.nih.gov/pubmed/34390326
http://dx.doi.org/10.1002/asia.202100684