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The Reaction of CO(2) with a Borylnitrene: Formation of an 3‐Oxaziridinone

The reaction of a borylnitrene with carbon dioxide is studied under cryogenic matrix isolation conditions. Photogenerated CatBN (Cat=catecholato) reacts with CO(2) under formation of the cycloaddition product CatBNCO(2), a 3‐oxaziridinone derivative, after photoexcitation (>550 nm). The product s...

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Detalles Bibliográficos
Autores principales: Bhagat, Virinder, Schumann, Julia, Bettinger, Holger F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596737/
https://www.ncbi.nlm.nih.gov/pubmed/34414646
http://dx.doi.org/10.1002/anie.202105171