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The Reaction of CO(2) with a Borylnitrene: Formation of an 3‐Oxaziridinone
The reaction of a borylnitrene with carbon dioxide is studied under cryogenic matrix isolation conditions. Photogenerated CatBN (Cat=catecholato) reacts with CO(2) under formation of the cycloaddition product CatBNCO(2), a 3‐oxaziridinone derivative, after photoexcitation (>550 nm). The product s...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596737/ https://www.ncbi.nlm.nih.gov/pubmed/34414646 http://dx.doi.org/10.1002/anie.202105171 |