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Breaking Symmetry Relaxes Structural and Magnetic Restraints, Suppressing QTM in Enantiopure Butterfly Fe(2)Dy(2) SMMs

The {Fe(2)Dy(2)} butterfly systems can show single molecule magnet (SMM) behaviour, the nature of which depends on details of the electronic structure, as previously demonstrated for the [Fe(2)Dy(2)(μ(3)‐OH)(2)(Me‐teaH)(2)(O(2)CPh)(6)] compound, where the [N,N‐bis‐(2‐hydroxyethyl)‐amino]‐2‐propanol...

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Detalles Bibliográficos
Autores principales: Baniodeh, Amer, Wagner, Danny, Peng, Yan, Kaemmerer, Hagen, Leblanc, Nicolas, Bräse, Stefan, Naubron, Jean‐Valére, Anson, Christopher E., Powell, Annie K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596739/
https://www.ncbi.nlm.nih.gov/pubmed/34617631
http://dx.doi.org/10.1002/chem.202103360