Low‐Valent Germanylidene Anions: Efficient Single‐Site Nucleophiles for Activation of Small Molecules

Rare mononuclear and helical chain low‐valent germanylidene anions supported by cyclic (alkyl)(amino)carbene and hypermetallyl ligands were synthesised by stepwise reduction from corresponding germylene precursors via stable and isolable germanium radicals. The electronic structures of the anions ca...

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Detalles Bibliográficos
Autores principales: Gendy, Chris, Mikko Rautiainen, J., Mailman, Aaron, Tuononen, Heikki M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596740/
https://www.ncbi.nlm.nih.gov/pubmed/34403540
http://dx.doi.org/10.1002/chem.202102804

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596740/
https://www.ncbi.nlm.nih.gov/pubmed/34403540
http://dx.doi.org/10.1002/chem.202102804

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