Cargando…

Low‐Valent Germanylidene Anions: Efficient Single‐Site Nucleophiles for Activation of Small Molecules

Rare mononuclear and helical chain low‐valent germanylidene anions supported by cyclic (alkyl)(amino)carbene and hypermetallyl ligands were synthesised by stepwise reduction from corresponding germylene precursors via stable and isolable germanium radicals. The electronic structures of the anions ca...

Descripción completa

Detalles Bibliográficos
Autores principales:	Gendy, Chris, Mikko Rautiainen, J., Mailman, Aaron, Tuononen, Heikki M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596740/ https://www.ncbi.nlm.nih.gov/pubmed/34403540 http://dx.doi.org/10.1002/chem.202102804

Ejemplares similares

High-Level Ab Initio Predictions of Thermochemical Properties of Organosilicon Species: Critical Evaluation of Experimental Data and a Reliable Benchmark Database for Extending Group Additivity Approaches
por: Vuori, Hannu T., et al.
Publicado: (2022)

Addition/Correction to “High-Level Ab Initio Predictions of Thermochemical Properties of Organosilicon Species: Critical Evaluation of Experimental Data and a Reliable Benchmark Database for Extending Group Additivity Approaches”
por: Vuori, Hannu T., et al.
Publicado: (2022)

Haptotropism in a Nickel Complex with a Neutral, π‐Bridging cyclo‐P(4) Ligand Analogous to Cyclobutadiene
por: Gendy, Chris, et al.
Publicado: (2022)

Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C–C bond activation
por: Helmer, Joschua, et al.
Publicado: (2022)

C–H activation and nucleophilic substitution in a photochemically generated high valent iron complex
por: Lim, Jia Hui, et al.
Publicado: (2018)

Ground State Destabilization by Anionic Nucleophiles Contributes to the Activity of Phosphoryl Transfer Enzymes
por: Andrews, Logan D., et al.
Publicado: (2013)

Examining the Influence of Anion Nucleophilicity on the Polymerisation Initiation Mechanism of Phenyl Glycidyl Ether
por: Binks, Fiona C., et al.
Publicado: (2019)

B−B Bond Nucleophilicity in a Tetraaryl μ‐Hydridodiborane(4) Anion
por: Trageser, Timo, et al.
Publicado: (2020)

The 9H‐9‐Borafluorene Dianion: A Surrogate for Elusive Diarylboryl Anion Nucleophiles
por: Gilmer, Jannik, et al.
Publicado: (2020)

Nucleophilic Substitution Reactions in the [B(3)H(8)](−) Anion in the Presence of Lewis Acids
por: Shulyak, Alexandra T., et al.
Publicado: (2022)

Efficient Colorimetric Fluoride Anion Sensor Based on π-Conjugated Carbazole Small Molecule
por: Deng, Zhifeng, et al.
Publicado: (2021)

Side‐on Coordination in Isostructural Nitrous Oxide and Carbon Dioxide Complexes of Nickel
por: Puerta Lombardi, Braulio M., et al.
Publicado: (2021)

Zero Valent Iron Nanoparticle-Loaded Nanobentonite Intercalated Carboxymethyl Chitosan for Efficient Removal of Both Anionic and Cationic Dyes
por: Eltaweil, Abdelazeem S., et al.
Publicado: (2021)

Efficient Removal of Ciprofloxacin from Contaminated Water via Polystyrene Anion Exchange Resin with Nanoconfined Zero-Valent Iron
por: Song, Yaqin, et al.
Publicado: (2022)

Completing the series of boron-nucleophilic cyanoborates: boryl anions of type NHC–B(CN)(2) (–)
por: Böser, Richard, et al.
Publicado: (2017)

Cobalt-Catalyzed Methoxycarbonylation of Substituted Dichlorobenzenes as an Example of a Facile Radical Anion Nucleophilic Substitution in Chloroarenes
por: Khaibulova, Tatyana S., et al.
Publicado: (2014)

Anionic Polymerization of β-Butyrolactone Initiated with Sodium Phenoxides. The Effect of the Initiator Basicity/Nucleophilicity on the ROP Mechanism
por: Domiński, Adrian, et al.
Publicado: (2019)

Surface-active ionic liquids in micellar catalysis: impact of anion selection on reaction rates in nucleophilic substitutions
por: Cognigni, Alice, et al.
Publicado: (2016)

Pyridylic anions are soft nucleophiles in the palladium-catalyzed C(sp(3))–H allylation of 4-alkylpyridines
por: Wasfy, Nour, et al.
Publicado: (2020)

G‐type Halohydrin Dehalogenases Catalyze Ring Opening Reactions of Cyclic Epoxides with Diverse Anionic Nucleophiles
por: Solarczek, Jennifer, et al.
Publicado: (2022)

Nucleophilic Isocyanation
por: Yurino, Taiga, et al.
Publicado: (2020)

The Role of Orbital Symmetries in Enforcing Ferromagnetic Ground State in Mixed Radical Dimers
por: Mansikkamäki, Akseli, et al.
Publicado: (2018)

Anion–cation contrast of small molecule solvation in salt solutions
por: Hervø-Hansen, Stefan, et al.
Publicado: (2022)

Reactions of aryl dimethylphosphinothioate esters with anionic oxygen nucleophiles: transition state structure in 70% water–30% ethanol
por: Kalu, Georgina I., et al.
Publicado: (2021)

On Terminal Alkynes That Can React with Active-Site Cysteine Nucleophiles in Proteases
por: Ekkebus, Reggy, et al.
Publicado: (2013)

Fabrication of Porous Hydrogenation Catalysts by a Selective Laser Sintering 3D Printing Technique
por: Lahtinen, Elmeri, et al.
Publicado: (2019)

Terbium Oxalatophosphonate as Efficient Multiresponsive Luminescent Sensors for Chromate Anions and Tryptophan Molecules
por: Jiao, Cheng-Qi, et al.
Publicado: (2018)

Small molecule anionophores promote transmembrane anion permeation matching CFTR activity
por: Hernando, Elsa, et al.
Publicado: (2018)

Small molecule anion carriers facilitate lactate transport in model liposomes and cells
por: Alonso-Carrillo, Daniel, et al.
Publicado: (2023)

Efficient Difluoromethylation of sp(3) Carbon Nucleophiles by Bromodifluoromethylation Reagents with Organic Bases
por: Liu, Guokai, et al.
Publicado: (2012)

Nucleophilic Functionalization of 2-R-3-Nitropyridines as a Versatile Approach to Novel Fluorescent Molecules
por: Nikol’skiy, Vladislav V., et al.
Publicado: (2022)

The Active Site Sulfenic Acid Ligand in Nitrile Hydratases Can Function as a Nucleophile
por: Martinez, Salette, et al.
Publicado: (2014)

Site‐Selective (Z)‐α‐Borylalkenyl Copper Systems for Nucleophilic Stereodefined Allylic Coupling
por: Pujol, Mireia, et al.
Publicado: (2022)

Chiral phosphines in nucleophilic organocatalysis
por: Xiao, Yumei, et al.
Publicado: (2014)

Nucleophilic arylation with tetraarylphosphonium salts
por: Deng, Zuyong, et al.
Publicado: (2016)

Concerted Nucleophilic Aromatic Substitutions
por: Kwan, Eugene E., et al.
Publicado: (2018)

Reactions of Polyfluorobenzenes With Nucleophilic Reagents
por: Wall, Leo A., et al.
Publicado: (1963)

Nucleophilicities and Nucleofugalities of Thio‐ and Selenoethers
por: Maji, Biplab, et al.
Publicado: (2021)

Renewable Reagent for Nucleophilic Fluorination
por: Alič, Blaž, et al.
Publicado: (2022)

Nucleophilic Substitution (S(N)2): Dependence on Nucleophile, Leaving Group, Central Atom, Substituents, and Solvent
por: Hamlin, Trevor A., et al.
Publicado: (2018)

Cannot write session to /tmp/vufind_sessions/sess_4vsfa6tihhggahmc3gptmj9efa