Hydrogenation of Secondary Amides using Phosphane Oxide and Frustrated Lewis Pair Catalysis

The metal‐free catalytic hydrogenation of secondary carboxylic acid amides is developed. The reduction is realized by two new catalytic reactions. First, the amide is converted into the imidoyl chloride by triphosgene (CO(OCCl(3))(2)) using novel phosphorus(V) catalysts. Second, the in situ generate...

Descripción completa

Detalles Bibliográficos
Autores principales: Köring, Laura, Sitte, Nikolai A., Bursch, Markus, Grimme, Stefan, Paradies, Jan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596796/
https://www.ncbi.nlm.nih.gov/pubmed/33460471
http://dx.doi.org/10.1002/chem.202100041

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596796/
https://www.ncbi.nlm.nih.gov/pubmed/33460471
http://dx.doi.org/10.1002/chem.202100041

Ejemplares similares