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Hydrogenation of Secondary Amides using Phosphane Oxide and Frustrated Lewis Pair Catalysis
The metal‐free catalytic hydrogenation of secondary carboxylic acid amides is developed. The reduction is realized by two new catalytic reactions. First, the amide is converted into the imidoyl chloride by triphosgene (CO(OCCl(3))(2)) using novel phosphorus(V) catalysts. Second, the in situ generate...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596796/ https://www.ncbi.nlm.nih.gov/pubmed/33460471 http://dx.doi.org/10.1002/chem.202100041 |