Hydroboration of Terminal Alkenes and trans‐1,2‐Diboration of Terminal Alkynes Catalyzed by a Manganese(I) Alkyl Complex

A Mn(I)‐catalyzed hydroboration of terminal alkenes and a 1,2‐diboration of terminal alkynes with pinacolborane (HBPin) is described. For alkenes, anti‐Markovnikov hydroboration takes place; for alkynes the reaction proceeds with excellent trans‐1,2‐selectivity. The most active pre‐catalyst is bench...

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Detalles Bibliográficos
Autores principales: Weber, Stefan, Zobernig, Daniel, Stöger, Berthold, Veiros, Luis F., Kirchner, Karl
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596825/
https://www.ncbi.nlm.nih.gov/pubmed/34435424
http://dx.doi.org/10.1002/anie.202110736

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596825/
https://www.ncbi.nlm.nih.gov/pubmed/34435424
http://dx.doi.org/10.1002/anie.202110736

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