Cargando…

Hydroboration of Terminal Alkenes and trans‐1,2‐Diboration of Terminal Alkynes Catalyzed by a Manganese(I) Alkyl Complex

A Mn(I)‐catalyzed hydroboration of terminal alkenes and a 1,2‐diboration of terminal alkynes with pinacolborane (HBPin) is described. For alkenes, anti‐Markovnikov hydroboration takes place; for alkynes the reaction proceeds with excellent trans‐1,2‐selectivity. The most active pre‐catalyst is bench...

Descripción completa

Detalles Bibliográficos
Autores principales:	Weber, Stefan, Zobernig, Daniel, Stöger, Berthold, Veiros, Luis F., Kirchner, Karl
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2021
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596825/ https://www.ncbi.nlm.nih.gov/pubmed/34435424 http://dx.doi.org/10.1002/anie.202110736

Ejemplares similares

Selective Manganese-Catalyzed Dimerization and Cross-Coupling of Terminal Alkynes
por: Weber, Stefan, et al.
Publicado: (2021)

Selective Transfer Semihydrogenation of Alkynes Catalyzed by an Iron PCP Pincer Alkyl Complex
por: Schratzberger, Heiko, et al.
Publicado: (2023)

Manganese-Catalyzed Dehydrogenative Silylation of Alkenes Following Two Parallel Inner-Sphere Pathways
por: Weber, Stefan, et al.
Publicado: (2021)

Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes
por: Smith, James R., et al.
Publicado: (2017)

Copper‐Photocatalyzed Hydroboration of Alkynes and Alkenes
por: Zhong, Mingbing, et al.
Publicado: (2021)

Asymmetric synthesis from terminal alkenes by diboration/cross-coupling cascades
por: Mlynarski, Scott N., et al.
Publicado: (2013)

Catalyst-free diboration and silaboration of alkenes and alkynes using bis(9-heterofluorenyl)s
por: Gilmer, Jannik, et al.
Publicado: (2023)

Selective Hydroboration–Oxidation of Terminal Alkenes under Flow Conditions
por: Elsherbini, Mohamed, et al.
Publicado: (2020)

Hydroxyl-Directed Stereoselective Diboration of Alkenes
por: Blaisdell, Thomas P., et al.
Publicado: (2014)

E-Selective Manganese-Catalyzed Semihydrogenation of Alkynes with H(2) Directly Employed or In Situ-Generated
por: Farrar-Tobar, Ronald A., et al.
Publicado: (2022)

Manganese‐Catalyzed Hydroborations with Broad Scope
por: Ghosh, Pradip, et al.
Publicado: (2021)

Homogeneous Manganese-Catalyzed Hydrofunctionalizations of Alkenes and Alkynes: Catalytic and Mechanistic Tendencies
por: Torres-Calis, Antonio, et al.
Publicado: (2022)

Computational design of high-performance ligand for enantioselective Markovnikov hydroboration of aliphatic terminal alkenes
por: Iwamoto, Hiroaki, et al.
Publicado: (2018)

Gold-catalyzed reaction of oxabicyclic alkenes with electron-deficient terminal alkynes to produce acrylate derivatives
por: Sun, Yin-wei, et al.
Publicado: (2013)

Electrochemical Hydroboration of Alkynes
por: Aelterman, Maude, et al.
Publicado: (2021)

Solvent-free hydroboration of alkynes catalyzed by an NHC–cobalt complex
por: Bołt, Małgorzata, et al.
Publicado: (2022)

Cation vacancy stabilization of single-atomic-site Pt(1)/Ni(OH)(x) catalyst for diboration of alkynes and alkenes
por: Zhang, Jian, et al.
Publicado: (2018)

Iron-catalyzed carboazidation of alkenes and alkynes
por: Xiong, Haigen, et al.
Publicado: (2019)

Manganese-Catalyzed Hydrogenation of Ketones under Mild and Base-free Conditions
por: Weber, Stefan, et al.
Publicado: (2021)

Palladium-catalyzed bisthiolation of terminal alkynes for the assembly of diverse (Z)-1,2-bis(arylthio)alkene derivatives
por: Lai, Yin-Long, et al.
Publicado: (2021)

Chemoselective Hydrogenation of Aldehydes under Mild, Base-Free Conditions: Manganese Outperforms Rhenium
por: Glatz, Mathias, et al.
Publicado: (2018)

Photoinduced Palladium‐Catalyzed Dicarbofunctionalization of Terminal Alkynes
por: Yang, Zhen, et al.
Publicado: (2021)

Enantioselective Cobalt-Catalyzed Hydroboration of Fluoroalkyl-Substituted Alkenes to Access Chiral Fluoroalkylboronates
por: Hu, Ming, et al.
Publicado: (2022)

Reaction Pathways and Redox States in α‐Selective Cobalt‐Catalyzed Hydroborations of Alkynes
por: Blasius, Clemens K., et al.
Publicado: (2020)

Palladium-catalyzed hydroboration reaction of unactivated alkynes with bis (pinacolato) diboron in water
por: Yang, Ming, et al.
Publicado: (2022)

Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes
por: Jin, Shengnan, et al.
Publicado: (2022)

Old Concepts, New Application – Additive‐Free Hydrogenation of Nitriles Catalyzed by an Air Stable Alkyl Mn(I) Complex
por: Weber, Stefan, et al.
Publicado: (2019)

Aluminum Amidinates: Insights into Alkyne Hydroboration
por: Hobson, Katie, et al.
Publicado: (2021)

Copper-catalyzed dehydrogenative borylation of terminal alkynes with pinacolborane
por: Romero, Erik A., et al.
Publicado: (2017)

Cobalt-catalyzed branched selective hydroallylation of terminal alkynes
por: Chen, Jieping, et al.
Publicado: (2022)

Manganese-catalyzed hydroboration of carbon dioxide and other challenging carbonyl groups
por: Erken, Christina, et al.
Publicado: (2018)

Late 3d Metal-Catalyzed (Cross-) Dimerization of Terminal and Internal Alkynes
por: Weber, Sebastian M., et al.
Publicado: (2021)

Nickel-Catalyzed 1,1-Aminoborylation of Unactivated Terminal Alkenes
por: Talavera, Laura, et al.
Publicado: (2023)

Highly Chemoselective Hydroboration of Alkynes and Nitriles Catalyzed by Group 4 Metal Amidophosphine–Borane Complexes
por: Bhattacharjee, Jayeeta, et al.
Publicado: (2020)

Publisher Correction: Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes
por: Jin, Shengnan, et al.
Publicado: (2022)

Rhodium‐Catalyzed Anti‐Markovnikov Transfer Hydroiodination of Terminal Alkynes
por: Boehm, Philip, et al.
Publicado: (2022)

Efficient Hydrogenation of Ketones and Aldehydes Catalyzed by Well-Defined Iron(II) PNP Pincer Complexes: Evidence for an Insertion Mechanism
por: Gorgas, Nikolaus, et al.
Publicado: (2014)

Ligand-controlled cobalt-catalyzed regiodivergent hydroboration of aryl,alkyl-disubstituted internal allenes
por: Wu, Caizhi, et al.
Publicado: (2020)

Enantioselective palladium-catalyzed diboration of 1,1-disubstituted allenes
por: Liu, Jiawang, et al.
Publicado: (2017)

Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes
por: Li, Lei, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_r6dedj3kbsa97dat6iefbqilbu