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Di‐tert‐butyldiphosphatetrahedrane as a Source of 1,2‐Diphosphacyclobutadiene Ligands

Reactions of di‐tert‐butyldiphosphatetrahedrane (1) with cycloocta‐1,5‐diene‐ or anthracene‐stabilised metalate anions of iron and cobalt consistently afford complexes of the rarely encountered 1,2‐diphosphacyclobutadiene ligand, which have previously been very challenging synthetic targets. The sub...

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Detalles Bibliográficos
Autores principales: Hierlmeier, Gabriele, Coburger, Peter, Scott, Daniel J., Maier, Thomas M., Pelties, Stefan, Wolf, Robert, Pividori, Daniel M., Meyer, Karsten, van Leest, Nicolaas P., de Bruin, Bas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596834/
https://www.ncbi.nlm.nih.gov/pubmed/34424579
http://dx.doi.org/10.1002/chem.202102335