The Archetypal Homoleptic Lanthanide Quadruple‐Decker—Synthesis, Mechanistic Studies, and Quantum Chemical Investigations

Reduction of [Sm(III)(COT(1,4‐SiiPr3))(BH(4))(thf)] (COT(1,4‐SiiPr3)=1,4‐(( i )Pr(3)Si)(3)C(8)H(6)) with KC(8) resulted in [Sm(III/II/III)(COT(1,4‐SiiPr3))(4)], the first example of a homoleptic lanthanide quadruple‐decker. As indicated by an analysis of the bond metrics in the solid‐state, the inne...

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Detalles Bibliográficos
Autores principales: Münzfeld, Luca, Hauser, Adrian, Hädinger, Pauline, Weigend, Florian, Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596981/
https://www.ncbi.nlm.nih.gov/pubmed/34486795
http://dx.doi.org/10.1002/anie.202111227

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596981/
https://www.ncbi.nlm.nih.gov/pubmed/34486795
http://dx.doi.org/10.1002/anie.202111227

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