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The Archetypal Homoleptic Lanthanide Quadruple‐Decker—Synthesis, Mechanistic Studies, and Quantum Chemical Investigations
Reduction of [Sm(III)(COT(1,4‐SiiPr3))(BH(4))(thf)] (COT(1,4‐SiiPr3)=1,4‐(( i )Pr(3)Si)(3)C(8)H(6)) with KC(8) resulted in [Sm(III/II/III)(COT(1,4‐SiiPr3))(4)], the first example of a homoleptic lanthanide quadruple‐decker. As indicated by an analysis of the bond metrics in the solid‐state, the inne...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596981/ https://www.ncbi.nlm.nih.gov/pubmed/34486795 http://dx.doi.org/10.1002/anie.202111227 |