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Metal‐to‐Metal Distance Modulated Au(I)/Ru(II) Cyclophanyl Complexes: Cooperative Effects in Photoredox Catalysis

The modular synthesis of Au(I)/Ru(II) decorated mono‐ and heterobimetallic complexes with π‐conjugated [2.2]paracyclophane is described. [2.2]Paracyclophane serves as a rigid spacer which holds the metal centers in precise spatial orientations and allows metal‐to‐metal distance modulation. A broad s...

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Detalles Bibliográficos
Autores principales: Zippel, Christoph, Israil, Roumany, Schüssler, Lars, Hassan, Zahid, Schneider, Erik K., Weis, Patrick, Nieger, Martin, Bizzarri, Claudia, Kappes, Manfred M., Riehn, Christoph, Diller, Rolf, Bräse, Stefan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8596992/
https://www.ncbi.nlm.nih.gov/pubmed/34655123
http://dx.doi.org/10.1002/chem.202102341